Googling for some good examples on how to implement a REST style service using WCF does not provide many useful hits. Microsoft seems to not like the acronym REST very well instead using either the term POX (plain old XML) or 'the Web Programming Model' (WPM???).
Anyway Bryan Bell has a pretty decent post showing the very basics of REST/POX/WPM as made available using WCF 3.5.
Read more on: http://hyperthink.net/blog/2007/03/05/HTTPPOX+Programming+Basics.aspx.